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The electronic properties of graphene are significantly influenced by the supporting substrate. [59] [60] The Si(100)/H surface does not perturb graphene's electronic properties, whereas the interaction between it and the clean Si(100) surface changes its electronic states significantly. This effect results from the covalent bonding between C ...
Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
Graphene (/ ˈ ɡ r æ f iː n /) [1] is a carbon allotrope consisting of a single layer of atoms arranged in a honeycomb planar nanostructure. [2] [3] The name "graphene" is derived from "graphite" and the suffix -ene, indicating the presence of double bonds within the carbon structure.
A two-dimensional semiconductor (also known as 2D semiconductor) is a type of natural semiconductor with thicknesses on the atomic scale. Geim and Novoselov et al. initiated the field in 2004 when they reported a new semiconducting material graphene, a flat monolayer of carbon atoms arranged in a 2D honeycomb lattice. [1]
Typical examples include graphene, topological insulators, bismuth antimony thin films and some other novel nanomaterials, [1] [4] [5] in which the electronic energy and momentum have a linear dispersion relation such that the electronic band structure near the Fermi level takes the shape of an upper conical surface for the electrons and a ...
So far, the graphene plasmonic effects have been demonstrated for different applications ranging from light modulation [15] [16] to biological/chemical sensing. [17] [18] [19] High-speed photodetection at 10 Gbit/s based on graphene and 20-fold improvement on the detection efficiency through graphene/gold nanostructure were also reported. [20]
For instance, Clar's rule can be used to predict several properties of graphene nanoribbons. [10] Aromatic π-sextets play an important part in the determination of the ground state of open shell biradical -type structures., [ 4 ] Clar's rule can rationalize the observed decrease in the bandgap of holey graphenes with increasing size.
A nanosheet is a two-dimensional nanostructure with thickness in a scale ranging from 1 to 100 nm. [1] [2] [3] A typical example of a nanosheet is graphene, the thinnest two-dimensional material (0.34 nm) in the world. [4] It consists of a single layer of carbon atoms with hexagonal lattices.