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This expression, also known as Duouglas-Doremus-Ojovan model, [67] can be motivated from various theoretical models of amorphous materials at the atomic level. [65] A two-exponential equation for the viscosity can be derived within the Dyre shoving model of supercooled liquids, where the Arrhenius energy barrier is identified with the high ...
A simple and widespread empirical correlation for liquid viscosity is a two-parameter exponential: = / This equation was first proposed in 1913, and is commonly known as the Andrade equation (named after British physicist Edward Andrade). It accurately describes many liquids over a range of temperatures.
The Vogel–Fulcher–Tammann equation, also known as Vogel–Fulcher–Tammann–Hesse equation or Vogel–Fulcher equation (abbreviated: VFT equation), is used to describe the viscosity of liquids as a function of temperature, and especially its strongly temperature dependent variation in the supercooled regime, upon approaching the glass transition.
The three viscosity equations now coalesce to a single viscosity equation = = because a nondimensional scaling is used for the entire viscosity equation. The standard nondimensionality reasoning goes like this: Creating nondimensional variables (with subscript D) by scaling gives
The viscosity of the sample is then calculated using the following equation: = ˙ where is the sample viscosity, and is the force applied to the sample to pull it apart. Much like the Meissner-type rheometer, the SER rheometer uses a set of two rollers to strain a sample at a given rate. [ 31 ]
Consequently, if a liquid has dynamic viscosity of n centiPoise, and its density is not too different from that of water, then its kinematic viscosity is around n centiStokes. For gas, the dynamic viscosity is usually in the range of 10 to 20 microPascal-seconds, or 0.01 to 0.02 centiPoise. The density is usually on the order of 0.5 to 5 kg/m^3.
In condensed matter physics and physical chemistry, the terms viscous liquid, supercooled liquid, and glass forming liquid are often used interchangeably to designate liquids that are at the same time highly viscous (see Viscosity of amorphous materials), can be or are supercooled, and able to form a glass.
The equation does not hold close to the pipe entrance. [8]: 3 The equation fails in the limit of low viscosity, wide and/or short pipe. Low viscosity or a wide pipe may result in turbulent flow, making it necessary to use more complex models, such as the Darcy–Weisbach equation.