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17 Cl chlorine; use (T/K) 128 139 153 ... The temperature at standard pressure should be equal to the normal boiling ... Section 6, Fluid Properties; Vapor Pressure
Chlorine, liquefied under a pressure of 7.4 bar at room temperature, displayed in a quartz ampule embedded in acrylic glass Gaseous chlorine stored inside a 500-mL water bottle. It is not recommended to store chlorine in this manner. Solid chlorine at −150 °C. Chlorine is the second halogen, being a nonmetal in
The atmospheric pressure boiling point of a liquid (also known as the normal boiling point) is the temperature at which the vapor pressure equals the ambient atmospheric pressure. With any incremental increase in that temperature, the vapor pressure becomes sufficient to overcome atmospheric pressure and cause the liquid to form vapor bubbles.
The vapor pressure chart to the right has graphs of the vapor pressures versus temperatures for a variety of liquids. [10] As can be seen in the chart, the liquids with the highest vapor pressures have the lowest normal boiling points. For example, at any given temperature, methyl chloride has the highest vapor pressure of any of the liquids in ...
In a binary boiling-point diagram, temperature (T ) (or sometimes pressure) is graphed vs. x 1. At any given temperature (or pressure) where both phases are present, vapor with a certain mole fraction is in equilibrium with liquid with a certain mole fraction. The two mole fractions often differ. These vapor and liquid mole fractions are ...
Lee [4] developed a modified form of the Antoine equation that allows for calculating vapor pressure across the entire temperature range using the acentric factor (𝜔) of a substance. The fundamental structure of the equation is based on the van der Waals equation and builds upon the findings of Wall [ 5 ] and Gutmann et al. [ 6 ] , who ...
However, its empirical value remains important: the unique combination of pressure and temperature at which liquid water, solid ice, and water vapor coexist in a stable equilibrium is approximately 273.16 ± 0.0001 K [4] and a vapor pressure of 611.657 pascals (6.11657 mbar; 0.00603659 atm).
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...