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A solid-state electrolyte (SSE) is a solid ionic conductor and electron-insulating material and it is the characteristic component of the solid-state battery. It is useful for applications in electrical energy storage (EES) in substitution of the liquid electrolytes found in particular in lithium-ion battery .
A polymer electrolyte is a polymer matrix capable of ion conduction. [1] Much like other types of electrolyte—liquid and solid-state—polymer electrolytes aid in movement of charge between the anode and cathode of a cell. [1] [2] [3] The use of polymers as an electrolyte was first demonstrated using dye-sensitized solar cells. [4]
A solid-state battery (SSB) is an electrical battery that uses a solid electrolyte for ionic conductions between the electrodes, instead of the liquid or gel polymer electrolytes found in conventional batteries. [1] Solid-state batteries theoretically offer much higher energy density than the typical lithium-ion or lithium polymer batteries. [2]
Solid-state ionics is the study of ionic-electronic mixed conductor and fully ionic conductors (solid electrolytes) and their uses. Some materials that fall into this category include inorganic crystalline and polycrystalline solids, ceramics, glasses, polymers, and composites.
Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors.
The main issues limiting actual performance are the high reactivity of naked fluoride in liquid electrolytes, low fluoride ionic conductivity of solid-state electrolytes at room temperature, and volume expansion of conversion-type electrodes that puts mechanical strain on cell components during charging-discharging cycling, leading to premature ...
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