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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
At extremely low P CO 2, dissolved CO 2, bicarbonate ion, and carbonate ion largely evaporate from the solution, leaving a highly alkaline solution of calcium hydroxide, which is more soluble than CaCO 3. For P CO 2 = 10 −12 atm, the [Ca 2+][OH −] 2 product is still below the solubility product of Ca(OH) 2 (8 × 10 −6).
The retrograde solubility of calcium sulfate is also responsible for its precipitation in the hottest zone of heating systems and for its contribution to the formation of scale in boilers along with the precipitation of calcium carbonate whose solubility also decreases when CO 2 degasses from hot water or can escape out of the system.
The term solubility is also used in some fields where the solute is altered by solvolysis. For example, many metals and their oxides are said to be "soluble in hydrochloric acid", although in fact the aqueous acid irreversibly degrades the solid to give soluble products. Most ionic solids dissociate when dissolved in polar solvents.
A carbonate is a salt of carbonic acid, (H 2 CO 3), [2] characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO 2− 3. The word "carbonate" may also refer to a carbonate ester , an organic compound containing the carbonate group O=C(−O−) 2 .
As the groundwater enters the cave, the excess carbon dioxide is released from the solution of the bicarbonate, causing the much less soluble calcium carbonate to be deposited. In the reverse process, dissolved carbon dioxide (CO 2) in rainwater (H 2 O) reacts with limestone calcium carbonate (CaCO 3) to form soluble calcium bicarbonate (Ca(HCO ...
Cold, dilute solutions of calcium chlorate and sulfuric acid react to give a precipitate of calcium sulfate and chloric acid in solution: [3] Ca(ClO 3) 2 + H 2 SO 4 → 2 HClO 3 + CaSO 4. Contact with strong sulfuric acid can result in explosions [4] due to the instability of concentrated chloric acid.