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In atomic physics and quantum chemistry, the Aufbau principle (/ ˈ aʊ f b aʊ /, from German: Aufbauprinzip, lit. ' building-up principle '), also called the Aufbau rule , states that in the ground state of an atom or ion , electrons first fill subshells of the lowest available energy , then fill subshells of higher energy.
As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2 , written as [Ar] 3d 4 4s 2 , but whose actual configuration given ...
The aufbau principle (from the German Aufbau, "building up, construction") was an important part of Bohr's original concept of electron configuration. It may be stated as: [ 12 ] a maximum of two electrons are put into orbitals in the order of increasing orbital energy: the lowest-energy subshells are filled before electrons are placed in ...
As an example, consider the ground state of silicon.The electron configuration of Si is 1s 2 2s 2 2p 6 3s 2 3p 2 (see spectroscopic notation).We need to consider only the outer 3p 2 electrons, for which it can be shown (see term symbols) that the possible terms allowed by the Pauli exclusion principle are 1 D , 3 P , and 1 S.
As a result of Hund's rule, constraints are placed on the way atomic orbitals are filled in the ground state using the Aufbau principle. Before any two electrons occupy an orbital in a subshell, other orbitals in the same subshell must first each contain one electron. Also, the electrons filling a subshell will have parallel spin before the ...
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The periodic table of electron configurations shows the arrangement of electrons in atoms, organized by increasing atomic number and chemical properties.
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