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where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
The definition of strain rate was first introduced in 1867 by American metallurgist Jade LeCocq, who defined it as "the rate at which strain occurs. It is the time rate of change of strain." In physics the strain rate is generally defined as the derivative of the strain with respect to time. Its precise definition depends on how strain is measured.
In mechanics, strain is defined as relative deformation, compared to a reference position configuration. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final configuration of the body and on whether the metric tensor or its dual is considered.
where is specific enthalpy, =: is dissipation function and is temperature. And where = (+) i.e. internal energy per unit volume equals mass density times the sum of: proper energy per unit mass, kinetic energy per unit mass, and gravitational potential energy per unit mass.
Slow strain rate testing (SSRT), also called constant extension rate tensile testing (CERT), is a popular test used by research scientists to study stress corrosion cracking. It involves a slow (compared to conventional tensile tests) dynamic strain applied at a constant extension rate in the environment of interest.
Such positive feedback leads to quick development of necking and leads to fracture. Note that though the pulling force is decreasing, the work strengthening is still progressing, that is, the true stress keeps growing but the engineering stress decreases because the shrinking section area is not considered. This region ends up with the fracture.
where: k 1 is the rate coefficient for the reaction that consumes A and B; k −1 is the rate coefficient for the backwards reaction, which consumes P and Q and produces A and B. The constants k 1 and k −1 are related to the equilibrium coefficient for the reaction (K) by the following relationship (set v=0 in balance):
In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical relationship between temperature and rate coefficient. It is usually designated by A when determined from experiment, while Z is usually left for collision frequency. The pre-exponential ...