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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
In even a slight presence of water, carbonic acid dehydrates to carbon dioxide and water, which then catalyzes further decomposition. [6] For this reason, carbon dioxide can be considered the carbonic acid anhydride. The hydration equilibrium constant at 25 °C is [H 2 CO 3]/[CO 2] ≈ 1.7×10 −3 in pure water [12] and ≈ 1.2×10 −3 in ...
The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls. [19]
To convert heat values to joules per mole values, multiply by 44.095 g/mol. To convert densities to moles per liter, multiply by 22.678 cm 3 mol/(L·g). Data obtained from CRC Handbook of Chemistry and Physics , 44th ed. pages 2560–2561, except for critical temperature line (31.1 °C) and temperatures −30 °C and below, which are taken from ...
[72] [73] [74] The isoelectric point of a given molecule is a function of its pK values, so different molecules have different isoelectric points. This permits a technique called isoelectric focusing , [ 75 ] which is used for separation of proteins by 2-D gel polyacrylamide gel electrophoresis .
Although solid magnesium reacts slowly with oxygen at STP, it is capable of burning in air, generating very high temperatures, and its metal powder may form explosive mixtures with air. Oxygen is present as compounds in the atmosphere in trace quantities in the form of carbon dioxide (CO 2) and oxides of nitrogen (NO x).
In the ink, it is mixed with sodium hydroxide, which reacts with carbon dioxide in the air. This reaction leads to the pH falling below the color change threshold as hydrogen ions are released by the reaction: OH − + CO 2 → CO 2− 3 (aq) + H + (aq).
The higher the proton affinity, the stronger the base and the weaker the conjugate acid in the gas phase.The (reportedly) strongest known base is the ortho-diethynylbenzene dianion (E pa = 1843 kJ/mol), [3] followed by the methanide anion (E pa = 1743 kJ/mol) and the hydride ion (E pa = 1675 kJ/mol), [4] making methane the weakest proton acid [5] in the gas phase, followed by dihydrogen.