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Complexes of vanadium(II) and (III) are relatively exchange inert and reducing. Those of V(IV) and V(V) are oxidants. Vanadium ion is rather large and some complexes achieve coordination numbers greater than 6, as is the case in [V(CN) 7] 4−. Oxovanadium(V) also forms 7 coordinate coordination complexes with tetradentate ligands and peroxides ...
Patrónite is the vanadium sulfide mineral with formula V S 4. The material is usually described as V 4+ (S 2 2−) 2. [6] Structurally, it is a "linear-chain" compound with alternating bonding and nonbonding contacts between the vanadium centers. The vanadium is octa-coordinated, which is an uncommon geometry for this metal. [7]
The concentration of vanadium in the blood of ascidian tunicates is as much as ten million times higher [specify] [102] [103] than the surrounding seawater, which normally contains 1 to 2 μg/L. [104] [105] The function of this vanadium concentration system and these vanadium-bearing proteins is still unknown, but the vanadocytes are later ...
Vanadium(III) sulfate is the inorganic compound with the formula V 2 (SO 4) 3. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green aquo complex [V(H 2 O) 6] 3+. The compound is prepared by treating V 2 O 5 in sulfuric acid with elemental sulfur: [2]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Vanadium(II) sulfate describes a family of inorganic compounds with the formula VSO 4 (H 2 O) x where 0 ≤ x ≤ 7. The hexahydrate is most commonly encountered. It is a violet solid that dissolves in water to give air-sensitive solutions of the aquo complex.
Sulfosalt minerals are sulfide minerals with the general formula A m B n X p, where A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanadium; B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium; X is sulfur or rarely selenium and/or ...
This hygroscopic blue solid is one of the most common sources of vanadium in the laboratory, reflecting its high stability. It features the vanadyl ion, VO 2+, which has been called the "most stable diatomic ion". [1] Vanadyl sulfate is an intermediate in the extraction of vanadium from petroleum residues, one commercial source of vanadium. [2]