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  2. Inductive effect - Wikipedia

    en.wikipedia.org/wiki/Inductive_effect

    In Organic chemistry, the inductive effect in a molecule is a local change in the electron density due to electron-withdrawing or electron-donating groups elsewhere in the molecule, resulting in a permanent dipole in a bond. [1] It is present in a σ (sigma) bond, unlike the electromeric effect which is present in a π (pi) bond.

  3. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    The inductive effect is the transmission of charge through covalent bonds and Bent's rule provides a mechanism for such results via differences in hybridisation. In the table below, [ 26 ] as the groups bonded to the central carbon become more electronegative, the central carbon becomes more electron-withdrawing as measured by the polar ...

  4. Taft equation - Wikipedia

    en.wikipedia.org/wiki/Taft_equation

    where ⁡ is the ratio of the rate of the substituted reaction compared to the reference reaction, ρ* is the sensitivity factor for the reaction to polar effects, σ* is the polar substituent constant that describes the field and inductive effects of the substituent, δ is the sensitivity factor for the reaction to steric effects, and E s is ...

  5. Electron-withdrawing group - Wikipedia

    en.wikipedia.org/wiki/Electron-withdrawing_group

    Electron-withdrawing groups exert an "inductive" or "electron-pulling" effect on covalent bonds. The strength of the electron-withdrawing group is inversely proportional to the pKa of the carboxylic acid. [2] The inductive effect is cumulative: trichloroacetic acid is 1000x stronger than chloroacetic acid.

  6. Hammett equation - Wikipedia

    en.wikipedia.org/wiki/Hammett_equation

    This effect is depicted in scheme 3, where, in a para substituted arene 1a, one resonance structure 1b is a quinoid with positive charge on the X substituent, releasing electrons and thus destabilizing the Y substituent. This destabilizing effect is not possible when X has a meta orientation. Scheme 3. Hammett Inductive Mesomeric Effects

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    If you suspect child abuse, call the Childhelp National Child Abuse Hotline at 1-800-4-A-Child or 1-800-422-4453, or go to www.childhelp.org. All calls are toll-free and confidential. The hotline ...

  8. Baker–Nathan effect - Wikipedia

    en.wikipedia.org/wiki/Baker–Nathan_effect

    In organic chemistry, the Baker–Nathan effect is observed with reaction rates for certain chemical reactions with certain substrates where the order in reactivity cannot be explained solely by an inductive effect of substituents. [1] This effect was described in 1935 by John W. Baker and W. S. Nathan.

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