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Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO 2. It is the peroxide (O 2 2−) salt of Ca 2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water. [3]
Reduction 4H + + 4e − → 2H 2 E° = 0.00 V vs. NHE Overall 2H 2 O → 2H 2 + O 2 E°cell = +1.23 V; ΔG = 475 kJ/mol . Water splitting can be done at higher pH values as well however the standard potentials will vary according to the Nernst equation and therefore shift by -59 mV for each pH unit increase. However, the total cell potential ...
Calcium oxalate crystals are commonly found in lichens, where they occur in two mineral forms: weddellite (CaC 2 O 4 ·(2+x)H 2 O) and whewellite (CaC 2 O 4 ·H 2 O). These crystals can form both on the surface of the lichen as a powdery coating called pruina and within the internal structures of the lichen thallus. The type and distribution of ...
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons ) of an atom in a chemical compound .
RMO = Ratio of the # of moles of oxygen to # of moles of oxidizable compound in their reaction to CO 2, water, and ammonia. For example, if a sample has 500 Wppm (Weight Parts per Million) of phenol: C 6 H 5 OH + 7O 2 → 6CO 2 + 3H 2 O COD = (500/94)·7·16*2 = 1192 Wppm
CaO (s) + H 2 O (l) ⇌ Ca(OH) 2 (aq) (ΔH r = −63.7 kJ/mol of CaO) As it hydrates, an exothermic reaction results and the solid puffs up. The hydrate can be reconverted to quicklime by removing the water by heating it to redness to reverse the hydration reaction.
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The intermediate formed reacts with water to liberate O 2. The cobalt-polyoxometalate complex [Co 4 (H 2 O) 2 (α-PW 9 O 34) 2] 10− is highly efficient WOC. [11] Some iron complexes catalyze water oxidation. A water-soluble complex [Fe(OTf) 2 (Me 2 Pytacn)] (Pytacn=pyridine-substituted trimethyltriazacyclononane; OTf= triflate) is an ...