Search results
Results from the WOW.Com Content Network
Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells. The rule states that for a given electron configuration , the lowest energy term is the one with the greatest value of spin multiplicity . [ 1 ]
The three rules are: [1] [2] [3] For a given electron configuration, the term with maximum multiplicity has the lowest energy. The multiplicity is equal to + , where is the total spin angular momentum for all electrons. The multiplicity is also equal to the number of unpaired electrons plus one. [4]
The superscript three (read as triplet) indicates that the multiplicity 2S+1 = 3, so that the total spin S = 1. This spin is due to two unpaired electrons, as a result of Hund's rule which favors the single filling of degenerate orbitals. The triplet consists of three states with spin components +1, 0 and –1 along the direction of the total ...
The graph crosses the x-axis at roots of odd multiplicity and does not cross it at roots of even multiplicity. A non-zero polynomial function is everywhere non-negative if and only if all its roots have even multiplicity and there exists an x 0 {\displaystyle x_{0}} such that f ( x 0 ) > 0 {\displaystyle f(x_{0})>0} .
This multiplicity notation for a partition can be written ... obeying various rules leads to a family of objects ... Archived from the original on 2021-12-11
Kasha's rule is a principle in the photochemistry of electronically excited molecules. The rule states that photon emission (fluorescence or phosphorescence) occurs in appreciable yield only from the lowest excited state of a given multiplicity. It is named after American spectroscopist Michael Kasha, who proposed it in 1950. [1] [2]
All results described in this article are based on Descartes' rule of signs. If p(x) is a univariate polynomial with real coefficients, let us denote by # + (p) the number of its positive real roots, counted with their multiplicity, [1] and by v(p) the number of sign variations in the sequence of its coefficients. Descartes's rule of signs ...
[10] [11] [12] This bound of the ... counted with multiplicity, ... For k = 0 and k = n, Descartes' rule of signs shows that the polynomial has exactly one positive ...