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In the study of heat transfer, Schwarzschild's equation [1] [2] [3] is used to calculate radiative transfer (energy transfer via electromagnetic radiation) through a medium in local thermodynamic equilibrium that both absorbs and emits radiation.
Radiative transfer (also called radiation transport) is the physical phenomenon of energy transfer in the form of electromagnetic radiation. The propagation of radiation through a medium is affected by absorption, emission, and scattering processes. The equation of radiative transfer describes these interactions mathematically. Equations of ...
Radiative heat transfer is the transfer of energy via thermal radiation, i.e., electromagnetic waves. [1] It occurs across vacuum or any transparent medium ( solid or fluid or gas ). [ 15 ] Thermal radiation is emitted by all objects at temperatures above absolute zero , due to random movements of atoms and molecules in matter.
Thermal radiation is one of the fundamental mechanisms of heat transfer, along with conduction and convection. The primary method by which the Sun transfers heat to the Earth is thermal radiation. This energy is partially absorbed and scattered in the atmosphere, the latter process being the reason why the sky is visibly blue. [3]
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
Note that the state equation, given by the first law of thermodynamics (i.e. conservation of energy), is written in the following form (assuming no mass transfer or radiation). This form is more general and particularly useful to recognize which property (e.g. c p or ρ {\displaystyle \rho } ) influences which term.
Gustav Kirchhoff (1824–1887) . In heat transfer, Kirchhoff's law of thermal radiation refers to wavelength-specific radiative emission and absorption by a material body in thermodynamic equilibrium, including radiative exchange equilibrium.
Note that the thermodynamic relations for the internal energy and enthalpy are given by: = + = + We may also obtain an equation for the kinetic energy by taking the dot product of the Navier-Stokes equation with the flow velocity to yield: = + The second term on the righthand side may be expanded to read: = () With the aid of the thermodynamic relation for enthalpy and the last result, we may ...