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Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
Despite the promising results in different cell studies and proof of concept studies, there is still incomplete understanding of the full biocompatibility of graphene-based materials. [192] Different cell lines react differently when exposed to graphene, and it has been shown that the lateral size of the graphene flakes, the form and surface ...
Graphene doped with various gaseous species (both acceptors and donors) can be returned to an undoped state by gentle heating in vacuum. [22] [24] Even for dopant concentrations in excess of 10 12 cm −2 carrier mobility exhibits no observable change. [24] Graphene doped with potassium in ultra-high vacuum at low temperature can reduce ...
Bilayer graphene displays the anomalous quantum Hall effect, a tunable band gap [3] and potential for excitonic condensation. [4] Bilayer graphene typically can be found either in twisted configurations where the two layers are rotated relative to each other or graphitic Bernal stacked configurations where half the atoms in one layer lie atop half the atoms in the other. [5]
So far, the graphene plasmonic effects have been demonstrated for different applications ranging from light modulation [15] [16] to biological/chemical sensing. [17] [18] [19] High-speed photodetection at 10 Gbit/s based on graphene and 20-fold improvement on the detection efficiency through graphene/gold nanostructure were also reported. [20]
Graphene nanoribbons (GNRs, also called nano-graphene ribbons or nano-graphite ribbons) are strips of graphene with width less than 100 nm. Graphene ribbons were introduced as a theoretical model by Mitsutaka Fujita and coauthors to examine the edge and nanoscale size effect in graphene.
These results not only advance the development of high-performance photodetectors based on the graphene/Si Schottky junction, but also have important implications for mass-production of graphene-based photodetector array devices for cost-effective environmental monitoring, medical images, free-space communications, photoelectric smart-tracking ...
Graphene has a high surface area, high electron mobility, and excellent chemical stability, making it an attractive substrate for SERS. Graphene-based SERS sensors have also been shown to be highly reproducible and stable, making them attractive for real-world applications. [ 45 ]