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Structure of the chitin molecule, showing two of the N-acetylglucosamine units that repeat to form long chains in β-(1→4)-linkage. Haworth projection of the chitin molecule. A close-up of the wing of a leafhopper; the wing is composed of chitin.
This layered structure is called peptidoglycan (formerly called murein). GlcNAc is the monomeric unit of the polymer chitin, which forms the exoskeletons of arthropods like insects and crustaceans. It is the main component of the radulas of mollusks, the beaks of cephalopods, and a major component of the cell walls of most fungi.
Chemically, chitin is a long-chain polymer of a N-acetylglucosamine, which is a derivative of glucose. The polymer bonds between the glucose units are β(1→4) links, the same as in cellulose. In its unmodified form, chitin is translucent, pliable, resilient and tough.
Chitin-glucan complex (CGC) is a copolymer (polysaccharide) that makes up fungal cell walls, consisting of covalently-bonded chitin and branched 1,3/1,6-ß-D-glucan. CGCs are alkaline - insoluble . Different species of fungi have different structural compositions of chitin and β-glucan making up the CGCs in their cell walls. [ 1 ]
Chemically, chitin is closely related to chitosan (a more water-soluble derivative of chitin). It is also closely related to cellulose in that it is a long unbranched chain of glucose derivatives. Both materials contribute structure and strength, protecting the organism. [32]
Homopolysaccharides are polysaccharides composed of a single type of sugar monomer. For example, cellulose is an unbranched homopolysaccharide made up of glucose monomers connected via beta-glycosidic linkages; glycogen is a branched form, where the glucose monomers are joined by alpha-glycosidic linkages.
Like cellulose, chitin is an abundant biopolymer that is relatively resistant to degradation. [17] Many mammals can digest chitin and the specific chitinase levels in vertebrate species are adapted to their feeding behaviours. [18] Certain fish are able to digest chitin. [19] Chitinases have been isolated from the stomachs of mammals, including ...
A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units. [23] Polystyrene is composed only of styrene-based repeat units, and is classified as a homopolymer.