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The mathematical formulation of quantum mechanics (QM) is built upon the concept of an operator. Physical pure states in quantum mechanics are represented as unit-norm vectors (probabilities are normalized to one) in a special complex Hilbert space. Time evolution in this vector space is given by the application of the evolution operator.
In classical mechanics, an observable is a real-valued "function" on the set of all possible system states, e.g., position and momentum. In quantum mechanics, an observable is an operator, or gauge, where the property of the quantum state can be determined by some sequence of operations.
The momentum operator can be described as a symmetric (i.e. Hermitian), unbounded operator acting on a dense subspace of the quantum state space. If the operator acts on a (normalizable) quantum state then the operator is self-adjoint. In physics the term Hermitian often refers to both symmetric and self-adjoint operators. [7] [8]
Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot.
In quantum mechanics, the position operator is the operator that corresponds to the position observable of a particle. When the position operator is considered with a wide enough domain (e.g. the space of tempered distributions ), its eigenvalues are the possible position vectors of the particle.
In quantum mechanics, a density matrix (or density operator) is a matrix that describes an ensemble [1] of physical systems as quantum states (even if the ensemble contains only one system). It allows for the calculation of the probabilities of the outcomes of any measurements performed upon the systems of the ensemble using the Born rule .
Since the operator is linear, they are valid for any linear combination of plane waves, and so they can act on any wave function without affecting the properties of the wave function or operators. Hence this must be true for any wave function. It turns out to work even in relativistic quantum mechanics, such as the Klein–Gordon equation above.
In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy.Its spectrum, the system's energy spectrum or its set of energy eigenvalues, is the set of possible outcomes obtainable from a measurement of the system's total energy.