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The expressions: a zeroth-order approximation, a first-order approximation, a second-order approximation, and so forth are used as fixed phrases. The expression a zero-order approximation is also common. Cardinal numerals are occasionally used in expressions like an order-zero approximation, an order-one approximation, etc.
The rate is first-order in one reactant (ethyl acetate), and also first-order in imidazole, which as a catalyst does not appear in the overall chemical equation. Another well-known class of second-order reactions are the S N 2 (bimolecular nucleophilic substitution) reactions, such as the reaction of n-butyl bromide with sodium iodide in acetone:
In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...
In mathematics, the moments of a function are certain quantitative measures related to the shape of the function's graph.If the function represents mass density, then the zeroth moment is the total mass, the first moment (normalized by total mass) is the center of mass, and the second moment is the moment of inertia.
Under zero-based numbering, the initial element is sometimes termed the zeroth element, [1] rather than the first element; zeroth is a coined ordinal number corresponding to the number zero. In some cases, an object or value that does not (originally) belong to a given sequence, but which could be naturally placed before its initial element ...
[1] [2] Thus, the rate equation is often shown as having first-order dependence on the substrate and zero-order dependence on the nucleophile. This relationship holds for situations where the amount of nucleophile is much greater than that of the intermediate. Instead, the rate equation may be more accurately described using steady-state kinetics.
I reviewed five kinds of canned chili from the supermarket to find the best-tasting option. The meat-free version of Amy's was quite tasty, but the Campbell's Chunky chili mac was my favorite.
First-order hold (FOH) is a mathematical model of the practical reconstruction of sampled signals that could be done by a conventional digital-to-analog converter (DAC) and an analog circuit called an integrator. For FOH, the signal is reconstructed as a piecewise linear approximation to the original signal that was sampled.