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These pigments enter a high-energy state upon absorbing a photon which they can release in the form of chemical energy. This can occur via light-driven pumping of ions across a biological membrane (e.g. in the case of the proton pump bacteriorhodopsin ) or via excitation and transfer of electrons released by photolysis (e.g. in the photosystems ...
A photosynthetic pigment (accessory pigment; chloroplast pigment; antenna pigment) is a pigment that is present in chloroplasts or photosynthetic bacteria and captures the light energy necessary for photosynthesis. List of photosynthetic pigments (in order of increasing polarity): Carotene: an orange pigment; Xanthophyll: a yellow pigment
The pigments which absorb light at the highest energy level are found furthest from the reaction center. On the other hand, the pigments with the lowest energy level are more closely associated with the reaction center. Energy will be efficiently transferred from the outer part of the antenna complex to the inner part.
Each photosystem II contains at least 99 cofactors: 35 chlorophyll a, 12 beta-carotene, two pheophytin, two plastoquinone, two heme, one bicarbonate, 20 lipids, the Mn 4 CaO 5 cluster (including two chloride ions), one non heme Fe 2+ and two putative Ca 2+ ions per monomer. [4] There are several crystal structures of photosystem II. [5]
Each antenna complex has between 250 and 400 pigment molecules and the energy they absorb is shuttled by resonance energy transfer to a specialized chlorophyll a at the reaction center of each photosystem. When either of the two chlorophyll a molecules at the reaction center absorb energy, an electron is excited and transferred to an electron ...
The light-harvesting system of PSI uses multiple copies of the same transmembrane proteins used by PSII. The energy of absorbed light (in the form of delocalized, high-energy electrons) is funneled into the reaction center, where it excites special chlorophyll molecules (P700, with maximum light absorption at 700 nm) to a higher energy level.
Each absorbed photon causes the formation of an exciton (an electron excited to a higher energy state) in the pigment molecule. The energy of the exciton is transferred to a chlorophyll molecule ( P680 , where P stands for pigment and 680 for its absorption maximum at 680 nm) in the reaction center of photosystem II via resonance energy transfer .
Eukaryotic photoautotrophs absorb photonic energy through the photopigment chlorophyll (a porphyrin derivative) in their endosymbiont chloroplasts, while prokaryotic photoautotrophs use chlorophylls and bacteriochlorophylls present in free-floating cytoplasmic thylakoids or, in rare cases, membrane-bound retinal derivatives such as ...