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Buckminsterfullerene is the most common naturally occurring fullerene. Small quantities of it can be found in soot. [5] [6] It also exists in space. Neutral C 60 has been observed in planetary nebulae [7] and several types of star. [8]
The calculated data allows using C 60 fullerene as a Faraday cage, [13] which isolates the encapsulated atom from the external electric field. The mentioned relations should be typical for the more complicated endohedral structures (e.g., C 60 @C 240 [14] and giant fullerene-containing "onions" [15]).
A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to six atoms.
Scheme 1 presents an overview of the first step, the creation of a 13 membered ring orifice on the fullerene surface. A 1,2,4-triazine 2 is fitted with two phenyl groups and a pyridine group for reasons of solubility and reacted in 1,2-dichlorobenzene with pristine C 60 fullerene 2 in a Diels-Alder reaction at high temperature and for an extended reaction time.
This page was last edited on 18 October 2024, at 13:16 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
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