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Astatine is known to bind to boron, [62] carbon, and nitrogen. [63] Various boron cage compounds have been prepared with At–B bonds, these being more stable than At–C bonds. [64] Astatine can replace a hydrogen atom in benzene to form astatobenzene C 6 H 5 At; this may be oxidized to C 6 H 5 AtCl 2 by chlorine.
Two-step procedures are used today, first synthesising stable astatoaryl prosthetic groups before incorporating them into the protein. [3] Not only is the C–At bond the weakest of all carbon–halogen bonds (following periodic trends), but also the bond easily breaks as the astatine is oxidised back to free astatine.
Astatine can replace a hydrogen atom in benzene to form astatobenzene C 6 H 5 At; this may be oxidized to C 6 H 5 AtCl 2 by chlorine. By treating this compound with an alkaline solution of hypochlorite, C 6 H 5 AtO 2 can be produced. [31] Astatine-labelled iodine reagents have been used to synthesise RAt, RAtCl 2, R 2 AtCl, and RAtO 2 (R ...
Number of isomers [3] [4] Number of isomers including stereoisomers [3] [5] Molecular Formula Name of straight chain Synonyms 1 1 1 CH 4: methane: methyl hydride; natural gas 2 1 1 C 2 H 6: ethane: dimethyl; ethyl hydride; methyl methane 3 1 1 C 3 H 8: propane: dimethyl methane; propyl hydride 4 2 2 C 4 H 10: n-butane: butyl hydride ...
Astatine has 23 nuclear isomers (nuclei with one or more nucleons – protons or neutrons – in an excited state). A nuclear isomer may also be called a " meta -state"; this means the system has more internal energy than the " ground state " (the state with the lowest possible internal energy), making the former likely to decay into the latter.
astatine-192m: 88 darmstadtium-271: 90 roentgenium-279: 90 carbon-18: 92 actinium-209: 92 polonium-191m: 93 actinium-208: 97 copernicium-284: 98 thorium-214: 100 flerovium-285: 100 protactinium-216: 105 nobelium-260: 106 astatine-204m: 108 astatine-212m1: 119 helium-8: 119 flerovium-286: 120 seaborgium-263m: 120 bismuth-191m: 124 carbon-9: 126 ...
Astatine monochloride [7] (AtCl) is made either by the direct combination of gas-phase astatine with chlorine or by the sequential addition of astatine and dichromate ion to an acidic chloride solution. Iodine monobromide (IBr) is made by the direct combination of the elements to form a dark red crystalline solid. It melts at 42 °C and boils ...
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