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Inert atmospheres consisting of gases such as argon, nitrogen, or helium are commonly used in chemical reaction chambers and in storage containers for oxygen-or water-sensitive substances, to prevent unwanted reactions of these substances with oxygen or water. [4] Argon is widely used in fluorescence tubes and low energy light bulbs.
Liquid nitrogen is a compact and readily transported source of dry nitrogen gas, as it does not require pressurization. Further, its ability to maintain temperatures far below the freezing point of water, specific heat of 1040 J ⋅kg -1 ⋅K -1 and heat of vaporization of 200 kJ⋅kg -1 makes it extremely useful in a wide range of applications ...
Because the liquid-to-gas expansion ratio of nitrogen is 1:694 at 20 °C, a tremendous amount of force can be generated if liquid nitrogen is rapidly vaporised in an enclosed space. In an incident on January 12, 2006, at Texas A&M University , the pressure-relief devices of a tank of liquid nitrogen were malfunctioning and later sealed.
[8] [20] The effect is applied in the Linde technique as a standard process in the petrochemical industry, where the cooling effect is used to liquefy gases, and in many cryogenic applications (e.g. for the production of liquid oxygen, nitrogen, and argon). A gas must be below its inversion temperature to be liquefied by the Linde cycle.
The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. [1] [2] Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N 2, 1% Ar in air) [3] and low relative cost.
Nitrogen is a liquid under −195.8 °C (77.3 K).. In physics, cryogenics is the production and behaviour of materials at very low temperatures.. The 13th International Institute of Refrigeration's (IIR) International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of "cryogenics" and "cryogenic" by accepting a threshold of 120 K (−153 °C) to ...
For most permanent gases, the minimum is below 120 °C. Often, the smaller the gas molecule (and the lower the gas solubility in water), the lower the temperature of the maximum of the Henry's law constant. Thus, the maximum is at about 30 °C for helium, 92 to 93 °C for argon, nitrogen and oxygen, and 114 °C for xenon. [12]
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...