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The oxide obtained from the basic carbonate is often most useful for catalysis. Basic nickel carbonate can be made by treating solutions of nickel sulfate with sodium carbonate: 4 Ni 2+ + CO 2− 3 + 6 OH − + 4 H 2 O → Ni 4 CO 3 (OH) 6 (H 2 O) 4. The hydrated carbonate has been prepared by electrolytic oxidation of nickel in the presence of ...
Gaspéite presence in the geologic environment may be used as an ore mining indicator of nickel rich minerals nearby. Gaspéite stones are used for carving ornamental objects and animal figurines, and are also cut and polished into attractive apple green color (often veined) cabochons for jewelry use. [citation needed]
Otwayite, Ni 2 CO 3 (OH) 2, is a hydrated nickel carbonate mineral. Otwayite is green, with a hardness of 4, a specific gravity of 3.4, and crystallises in the orthorhombic system. Occurrence
Nickel is preeminently an alloy metal, and its chief use is in nickel steels and nickel cast irons, in which it typically increases the tensile strength, toughness, and elastic limit. It is widely used in many other alloys, including nickel brasses and bronzes and alloys with copper, chromium, aluminium, lead, cobalt, silver, and gold ( Inconel ...
Where the Negishi coupling is rarely used in industrial chemistry, a result of the aforementioned water and oxygen sensitivity, it finds wide use in the field of natural products total synthesis. The increased reactivity relative to other cross-coupling reactions makes the Negishi coupling ideal for joining complex intermediates in the ...
Nickel hydroxides are used in nickel–cadmium and Nickel–metal hydride batteries. Nickel(II) hydroxide Ni(OH) 2, the main hydroxide of nickel is coloured apple green. It is known as the mineral theophrastite. β-NiO(OH) is a black powder with nickel in the +3 oxidation state.
Nickel maleate can be made from maleic acid and nickel carbonate in boiling water. A dihydrate crystallises from the water solution. [11] Nickel fumarate prepared from fumaric acid and nickel carbonate is pale green as a tetrahydrate, and mustard coloured as an anhydride. It decomposes when heated to 300° to 340° in vacuum.
Hellyerite, NiCO 3 ·6(H 2 O), is an hydrated nickel carbonate mineral. It is light blue to bright green in colour, has a hardness of 2.5, a vitreous luster, a white streak and crystallises in the monoclinic system. The crystal habit is as platy and mammillary encrustations on its matrix. It is a pentahydrate according to X-ray crystallography.