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Radical elimination can be viewed as the reverse of radical addition. In radical elimination, an unstable radical compound breaks down into a spin-paired molecule and a new radical compound. Shown below is an example of a radical elimination reaction, where a benzoyloxy radical breaks down into a phenyl radical and a carbon dioxide molecule. [7]
A trivalent group 14 radical (also known as a trivalent tetrel radical) is a molecule that contains a group 14 element (E = C, Si, Ge, Sn, Pb) with three bonds and a free radical, having the general formula of R 3 E•. Such compounds can be categorized into three different types, depending on the structure (or equivalently the orbital in which ...
In the third type of substitution reaction, radical substitution, the attacking particle is a radical. [44] This process usually takes the form of a chain reaction, for example in the reaction of alkanes with halogens. In the first step, light or heat disintegrates the halogen-containing molecules producing radicals.
The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5] This makes it a very dangerous compound to the organism. [6] [7] Unlike superoxide, which can be detoxified by superoxide dismutase, the hydroxyl radical cannot be eliminated by an enzymatic reaction.
Radical theory is an obsolete scientific theory in chemistry describing the structure of organic compounds.The theory was pioneered by Justus von Liebig, Friedrich Wöhler and Auguste Laurent around 1830 and is not related to the modern understanding of free radicals.
In spectroscopy and quantum chemistry, the multiplicity of an energy level is defined as 2S+1, where S is the total spin angular momentum. [1] [2] [3] States with ...
The triphenylmethyl radical (often shortened to trityl radical after 1927 suggestion by Helferich et al. [1]) is an organic compound with the formula (C 6 H 5) 3 C. It is a persistent radical. It was the first radical ever to be described in organic chemistry. Because of its accessibility, the trityl radical has been heavily exploited. [2]
In chemistry, a radical clock is a chemical compound that assists in the indirect methodology to determine the kinetics of a free-radical reaction. The radical-clock compound itself reacts at a known rate, which provides a calibration for determining the rate of another reaction.