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Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction. [5] The reaction mechanism of carbon dioxide with soda lime can be decomposed in three elementary steps:
As lime in the form of limewater is added to raw water, the pH is raised and the equilibrium of carbonate species in the water is shifted. Dissolved carbon dioxide (CO 2) is changed into bicarbonate (HCO − 3) and then carbonate (CO 2-3). This action causes calcium carbonate to precipitate due to exceeding the solubility product.
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
As it hydrates, an exothermic reaction results and the solid puffs up. The hydrate can be reconverted to quicklime by removing the water by heating it to redness to reverse the hydration reaction. One litre of water combines with approximately 3.1 kilograms (6.8 lb) of quicklime to give calcium hydroxide plus 3.54 MJ of energy.
Rain water contains dissolved carbon dioxide taken from the atmosphere. Some of the dissolved carbon dioxide reacts with the water to form carbonic acid, which remains in solution. Minerals containing calcium and magnesium form soluble bicarbonates when exposed to carbonic acid. Water containing these minerals is known as "hard water".
Pure lime is soluble in water containing carbonic acid, a natural, weak acid which is a solution of carbon dioxide in water and acid rain so it will slowly wash away, but this characteristic also produces autogenous or self-healing process where the dissolved lime can flow into cracks in the material and be redeposited, automatically repairing ...
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Gas exsolution can also occur when the confining pressure is released such as removing the top off a beer bottle or where subsurface water is flowed into an atmospheric pressure tank. As new cold water with dissolved calcium carbonate/bicarbonate is added and heated, the process continues: CO 2 gas is again removed, carbonate concentration ...