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For example, the electron wave function for an unexcited hydrogen atom is a spherically symmetric function known as an s orbital . Analytic solutions of the Schrödinger equation are known for very few relatively simple model Hamiltonians including the quantum harmonic oscillator , the particle in a box , the dihydrogen cation , and the ...
Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
The concept that matter behaves like a wave was proposed by French physicist Louis de Broglie (/ d ə ˈ b r ɔɪ /) in 1924, and so matter waves are also known as de Broglie waves. The de Broglie wavelength is the wavelength , λ , associated with a particle with momentum p through the Planck constant , h : λ = h p . {\displaystyle \lambda ...
However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found. These quantum-mechanical systems with analytical solutions are listed below.
In a mechanical wave, stress and strain fields oscillate about a mechanical equilibrium. A mechanical wave is a local deformation (strain) in some physical medium that propagates from particle to particle by creating local stresses that cause strain in neighboring particles too. For example, sound waves are variations of the local pressure and ...
Semi-empirical quantum chemistry methods Møller–Plesset perturbation theory Configuration interaction Coupled cluster Multi-configurational self-consistent field Quantum chemistry composite methods Quantum Monte Carlo: Density functional theory; Time-dependent density functional theory Thomas–Fermi model Orbital-free density functional theory
In theoretical physics, the pilot wave theory, also known as Bohmian mechanics, was the first known example of a hidden-variable theory, presented by Louis de Broglie in 1927. Its more modern version, the de Broglie–Bohm theory , interprets quantum mechanics as a deterministic theory, and avoids issues such as wave function collapse , and the ...
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles.By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon.