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Hematite (/ ˈ h iː m ə ˌ t aɪ t, ˈ h ɛ m ə-/), also spelled as haematite, is a common iron oxide compound with the formula, Fe 2 O 3 and is widely found in rocks and soils. [6] Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe 2 O 3. It has the same crystal structure as corundum ...
The ratio of Fe 2+ to Fe 3+ within a rock determines, in part, the silicate mineral and oxide mineral assemblage of the rock. Within a rock of a given chemical composition, iron enters minerals based on the bulk chemical composition and the mineral phases which are stable at that temperature and pressure.
More recently the term has also been used to describe a wide variety of rocks containing similar carbon layers, leading to some confusion. In scientific usage, shungite refers to a mineraloid which contains >98% carbon, and is used as a modifier to the host-rock's name, i.e. "shungite-bearing dolostone". [ 10 ]
A common form is held by the mineral hematite, another iron oxide. Hematite forms through chemical oxidation reactions of other minerals in the rock including magnetite. Red beds, clastic sedimentary rocks (such as sandstones) are red because of hematite that formed during sedimentary diagenesis. The CRM signatures in red beds can be quite ...
Some examples of minerals in iron-rich rocks containing oxides are limonite, hematite, and magnetite. An example of a mineral in iron-rich rock containing carbonates is siderite and an example of minerals in an iron-rich rock containing silicate is chamosite. [2] They are often interbedded with limestones, shales, and fine-grained sandstones.
Jaspillite (or jaspilite), also called itabirite or jasper taconite, is a chemical rock formed similar to chert, but is generally quite iron-rich. Jaspillite is typically a banded mixture of hematite and quartz common in the banded iron formation rocks of Proterozoic and Archaean age in the Canadian Shield .
Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the mineral pair forms a buffer that can control how oxidizing its environment is (the oxygen fugacity). This buffer is known as the hematite-magnetite or HM buffer.
Metasomatism (from the Greek μετά metá "change" and σῶμα sôma "body") is the chemical alteration of a rock by hydrothermal and other fluids. [1] It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. [2]
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