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Fluorobenzaldehyde isomers Name o-Fluorobenzaldehyde m-Fluorobenzaldehyde p-Fluorobenzaldehyde Structure: Systematic name: 2-Fluorobenzaldehyde 3-Fluorobenzaldehyde 4-Fluorobenzaldehyde Molecular formula: C 7 H 5 FO C 7 H 5 FO C 7 H 5 FO Molar mass: 124.11 g/mol 124.11 g/mol 124.11 g/mol CAS number: 446-52-6 456-48-4 459-57-4 EC number 207-171 ...
The inductive and resonance properties compete with each other but the resonance effect dominates for purposes of directing the sites of reactivity. For nitration, for example, fluorine directs strongly to the para position because the ortho position is inductively deactivated (86% para, 13% ortho, 0.6% meta).
2-Chloro-6-fluorobenzaldehyde is prepared by oxidation of 2-chloro-6-fluorotolulene by chromyl chloride. [3] It reacts with sodium hydroxide to give a mixture of 2-chloro-6-fluorobenzene and 6-chlorosalicaldehyde. [4] 2-Chloro-6-fluorobenzaldehyde is used in the production of the antiseptics dicloxacillin and flucloxacillin.
The isomers which have been cited as examples of metamers in chemical literature consist primarily of ethers; [3] but this could by the same reasoning be extended to thioethers, secondary as well as tertiary amines, esters, secondary as well as tertiary amides, (mixed) acid anhydrides etc. Metamers in organic chemistry
PhF behaves rather differently from other halobenzene derivatives owing to the pi-donor properties of fluoride. For example, the para position is more activated than benzene toward electrophiles. For this reason, it can be converted to 1-bromo-4-fluorobenzene with relatively high efficiency. [3]
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Care must be taken to avoid cocrystallisation of the ortho isomer. [2] Many nitro compounds' ortho and para isomers have quite different boiling points. These isomers can often be separated by distillation. These separated isomers can be converted to diazonium salts and used to prepare other pure ortho or para compounds. [3]
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