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Sulfur trioxide is a reagent in sulfonation reactions. Dimethyl sulfate is produced commercially by the reaction of dimethyl ether with sulfur trioxide: [20] CH 3 OCH 3 + SO 3 → (CH 3) 2 SO 4. Sulfate esters are used as detergents, dyes, and pharmaceuticals. Sulfur trioxide is generated in situ from sulfuric acid or is used as a solution in ...
Oleum (Latin oleum, meaning oil), or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid (also known as pyrosulfuric acid). [1] Oleums can be described by the formula ySO 3 ·H 2 O where y is the
Sulfur trioxide is the active ingredient in many sulfonation reactions. Typical conditions involve heating the aromatic compound with sulfuric acid: [2] C 6 H 6 + H 2 SO 4 → C 6 H 5 SO 3 H + H 2 O. Sulfur trioxide or its protonated derivative is the actual electrophile in this electrophilic aromatic substitution.
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
The industrial synthesis entails the reaction of hydrogen chloride with a solution of sulfur trioxide in sulfuric acid: [7] HCl + SO 3 → ClSO 3 H It can also be prepared by the method originally used by acid's discoverer Alexander William Williamson in 1854, [ 4 ] namely chlorination of sulfuric acid, written here for pedagogical purposes as ...
The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively. [1] The procedure uses dimethyl sulfoxide (DMSO) as the oxidant and the solvent, activated by the sulfur trioxide pyridine complex (SO 3 •C 5 H 5 N) in the presence of triethylamine or diisopropylethylamine as base.
The foremost challenge in catalytic oxidation is the conversion of methane to methanol. Most methane is stranded, i.e. not located near metropolitan areas. Consequently, it is flared (converted to carbon dioxide). One challenge is that methanol is more easily oxidized than is methane. [3]
Sulfamic acid is produced industrially by treating urea with a mixture of sulfur trioxide and sulfuric acid (or oleum). The conversion is conducted in two stages, the first being sulfamation: OC(NH 2) 2 + SO 3 → OC(NH 2)(NHSO 3 H) OC(NH 2)(NHSO 3 H) + H 2 SO 4 → CO 2 + 2 H 3 NSO 3. In this way, approximately 96,000 tonnes were produced in ...