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Pentane-2,4-dione (keto form) Other names ... Hacac; 2,4-Pentanedione; Identifiers CAS Number. 123-54-6 ... In some cases the chelate effect is so strong that no ...
Pentanedione may refer to: Acetylacetone (2,4-pentanedione) Acetylpropionyl (2,3-pentanedione) See also. C 5 H 8 O 2; Cyclopentanedione
2-Methyl-2,4-pentanediol (MPD) is an organic compound with the formula (CH 3) 2 C(OH)CH 2 CH(OH)CH 3. This colourless liquid is a chiral diol . It is produced industrially from diacetone alcohol by hydrogenation . [ 4 ]
Aside from these effects, there is often also a steric effect, due to increased steric hindrance at the ortho position but not the para position, leading to a larger amount of the para product. The effect is illustrated for electrophilic aromatic substitutions with alkyl substituents of differing steric demand for electrophilic aromatic nitration.
Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
In particular, 13 C quaternary carbons suffer from low signal intensity due to long relaxation times and lack of enhancement from the Nuclear Overhauser effect. To circumvent the first issue, the addition of a small quantity (on the order of 0.1 mM) of Cr(acac) 3 to an NMR sample reduces the relaxation time by providing an alternative ...
The term ordinary Hall effect can be used to distinguish the effect described in the introduction from a related effect which occurs across a void or hole in a semiconductor or metal plate when current is injected via contacts that lie on the boundary or edge of the void. The charge then flows outside the void, within the metal or semiconductor ...
2,4-Dimethylpentane is an alkane with the chemical formula [(H 3 C) 2 CH] 2 CH 2. This colorless hydrocarbon is produced in large quantities in oil refineries. It results from the alkylation of isobutane by propylene. [1] Often referred to as "alkylate", it is blended with other gasoline components to give a high octane fuel.