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Tantalum is a chemical element; it has symbol Ta and atomic number 73. Previously known as tantalium, [citation needed] it is named after Tantalus, a figure in Greek mythology. [11] Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that is highly corrosion-resistant.
[119] [120] [121] For oral administration the toxicity is lower; a study with rats yielded a LD 50 after seven days of 940 mg/kg. [119] Compounds containing tantalum are rarely encountered in the laboratory, and it and its compounds rarely cause injury, and when they do, the injuries are normally rashes. [19]
Tantalum pentoxide, also known as tantalum(V) oxide, is the inorganic compound with the formula Ta 2 O 5. It is a white solid that is insoluble in all solvents but is attacked by strong bases and hydrofluoric acid. Ta 2 O 5 is an inert material with a high refractive index and low absorption (i.e. colourless), which makes it useful for coatings ...
Tantalum alkylidene complexes arise by treating trialkyltantalum dichloride with alkyl lithium reagents. This reaction initially forms a thermally unstable tetraalkyl-monochloro-tantalum complex, which undergoes α-hydrogen elimination, followed by alkylation of the remaining chloride.
With the addition of squarate or perchlorate, the tantalum complex dimerises in acetonitrile, with their respective chelating ligands bridging the Ta centres. These seven-coordinate complexes of the form TaMe 3 L 2 , where L is a bidentate monoanion, are markedly more thermally stable than their precursor, decomposing in the range 80 - 120°C.
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Tantalum pentachloride can be prepared by reacting powdered metallic tantalum with chlorine gas at between 170 and 250 °C. This reaction can also be performed using HCl at 400 °C. [4] 2 Ta + 5 Cl 2 → 2 TaCl 5 2 Ta + 10 HCl → 2 TaCl 5 + 5 H 2. It can also be prepared by a reaction between tantalum pentoxide and thionyl chloride at 240 °C
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