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Enthalpy (/ ˈ ɛ n θ əl p i / ⓘ) is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. [1] It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere.
The British imperial units and U.S. customary units for both energy and work include the foot-pound force (1.3558 J), the British thermal unit (BTU) which has various values in the region of 1055 J, the horsepower-hour (2.6845 MJ), and the gasoline gallon equivalent (about 120 MJ).
The standard enthalpy of formation is measured in units of energy per amount of substance, usually stated in kilojoule per mole (kJ mol −1), but also in kilocalorie per mole, joule per mole or kilocalorie per gram (any combination of these units conforming to the energy per mass or amount guideline).
In an isenthalpic process, system enthalpy (H) is constant. In the case of free expansion for an ideal gas, there are no molecular interactions, and the temperature remains constant. For real gasses, the molecules do interact via attraction or repulsion depending on temperature and pressure, and heating or cooling does occur.
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
Simple English; Slovenčina ... H is the enthalpy (SI unit: joule). The expression for the infinitesimal reversible change in the Gibbs free energy as a function of ...
The entropy unit is a non-S.I. unit of thermodynamic entropy, usually denoted by "e.u." or "eU" and equal to one calorie per kelvin per mole, or 4.184 joules per kelvin per mole. [1] Entropy units are primarily used in chemistry to describe enthalpy changes.
Units for other physical quantities are derived from this set as needed. In English Engineering Units, the pound-mass and the pound-force are distinct base units, and Newton's Second Law of Motion takes the form = where is the acceleration in ft/s 2 and g c = 32.174 lb·ft/(lbf·s 2).