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  2. Organozinc chemistry - Wikipedia

    en.wikipedia.org/wiki/Organozinc_chemistry

    These structures cause zinc to have two bonding d-orbitals and three low-lying non-bonding d-orbitals (see non-bonding orbital), which are available for binding. When zinc lacks electron donating ligands it is unable to obtain coordination saturation, which is a consequence of the large atomic radius and low electron deficiency of zinc.

  3. Single displacement reaction - Wikipedia

    en.wikipedia.org/wiki/Single_displacement_reaction

    A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group.

  4. Kirkendall effect - Wikipedia

    en.wikipedia.org/wiki/Kirkendall_effect

    The Kirkendall effect is the motion of the interface between two metals that occurs due to the difference in diffusion rates of the metal atoms. The effect can be observed, for example, by placing insoluble markers at the interface between a pure metal and an alloy containing that metal, and heating to a temperature where atomic diffusion is reasonable for the given timescale; the boundary ...

  5. Displacement chromatography - Wikipedia

    en.wikipedia.org/wiki/Displacement_chromatography

    Displacement chromatography is a chromatography technique in which a sample is placed onto the head of the column [n 1] and is then displaced by a solute that is more strongly sorbed than the components of the original mixture.

  6. Equivalent weight - Wikipedia

    en.wikipedia.org/wiki/Equivalent_weight

    For example, 50 g of zinc will react with oxygen to produce 62.24 g of zinc oxide, implying that the zinc has reacted with 12.24 g of oxygen (from the Law of conservation of mass): the equivalent weight of zinc is the mass which will react with eight grams of oxygen, hence 50 g × 8 g/12.24 g = 32.7 g.

  7. Salt metathesis reaction - Wikipedia

    en.wikipedia.org/wiki/Salt_metathesis_reaction

    Salt metathesis is a common technique for exchanging counterions.The choice of reactants is guided by a solubility chart or lattice energy. HSAB theory can also be used to predict the products of a metathesis reaction.

  8. Leaching (metallurgy) - Wikipedia

    en.wikipedia.org/wiki/Leaching_(metallurgy)

    A good example of the autoclave leach process can also be found in the metallurgy of zinc. It is best described by the following chemical reaction: [citation needed] 2 ZnS + O 2 + 2 H 2 SO 4 → 2 ZnSO 4 + 2 H 2 O + 2 S. This reaction proceeds at temperatures above the boiling point of water, thus creating a vapour pressure inside the vessel.

  9. Zinc smelting - Wikipedia

    en.wikipedia.org/wiki/Zinc_smelting

    Zinc smelting is the process of converting zinc concentrates (ores that contain zinc) into pure zinc. Zinc smelting has historically been more difficult than the smelting of other metals, e.g. iron , because in contrast, zinc has a low boiling point .