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A solid-state electrolyte (SSE) is a solid ionic conductor and electron-insulating material and it is the characteristic component of the solid-state battery. It is useful for applications in electrical energy storage (EES) in substitution of the liquid electrolytes found in particular in lithium-ion battery.
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li + ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life.
Aqueous Li-ion batteries have been of great interest for military use due to their safety and durability. Unlike the high voltage yet volatile non-aqueous Li-ion batteries, aqueous Li-ion batteries have the potential to serve as a more reliable energy source on the battlefield, because external damage to the battery would not diminish performance or cause it to explode.
A lithium polymer battery, or more correctly, lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly, and others), is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrolyte. Highly conductive semisolid polymers form this electrolyte.
This forms the solid electrolyte used for ion conduction between anode and cathode. [4] [5] LiBON, lithium boron oxynitride, is another amorphous glassy material used as a solid electrolyte material in thin film flexible batteries. [6] Solid polymer electrolytes offer several advantages in comparison to a classical liquid lithium-ion battery.
In batteries, two materials with different electron affinities are used as electrodes; electrons flow from one electrode to the other outside of the battery, while inside the battery the circuit is closed by the electrolyte's ions. Here, the electrode reactions convert chemical energy to electrical energy.
Lithium-ion batteries were first proposed in a 1949 French patent. Research and development began in the 1960s. These batteries initially used organic liquid electrolytes, which faced two main issues: organic electrolytes and lithium metal were unstable together, and dendrites grew during cycling, which could lead to short circuits.
Lithium iodide is used as a solid-state electrolyte for high-temperature batteries. It is also the standard electrolyte in artificial pacemakers [6] due to the long cycle life it enables. [7] The solid is used as a phosphor for neutron detection. [8] It is also used, in a complex with Iodine, in the electrolyte of dye-sensitized solar cells.
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