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Because electrolytically zinc-plated surfaces provide comparatively little corrosion protection, and in the case of galvanic zinc coatings on high-strength steel (e.g. category 10.9 and 12.9 high-strength bolts) there is a risk of hydrogen embrittlement, the industry needed a better corrosion protection system.
This process is done by putting zinc or a zinc plated metal in a solution of sodium dichromate and sulfuric acid for a few seconds. [6] Zinc chromate can also be synthesized by using neutral potassium chromate (K 2 CrO 4) and zinc sulfate (ZnSO 4), which forms a precipitate. [7] K 2 CrO 4 + ZnSO 4 → ZnCrO 4 + K 2 SO 4
It is constructed of steel or stainless steel and lined with an acid and abrasion resistant material, such as neoprene, polypropylene, and polybutylene. The barrel sizes range from 0.04–1.13 m 3 (1.4–39.9 cu ft), however the working volume is only 25 to 35% of the total volume. For most plating applications the tumbler is rotated at 60 RPM ...
Galvanization (also spelled galvanisation) [1] is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are coated by submerging them in a bath of hot, molten zinc. [citation needed]
The chromate coating acts as paint does, protecting the zinc from white corrosion, thus making the part considerably more durable, depending on the chromate layer's thickness. [ 8 ] [ 9 ] [ 10 ] The protective effect of chromate coatings on zinc is indicated by color, progressing from clear/blue to yellow, gold, olive drab and black.
This improvement was discovered by Darsey of the Parker Rust Proof Company, who filed a patent in February 1941, which was granted in August 1942, U.S. patent 2,293,716, that improved upon the zinc phosphatizing (Parkerizing) process further. He discovered that adding copper reduced the acidity requirement over what had been required, and that ...
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