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Direct interactions are between adjacent adsorbed molecules, which could make adsorbing near another adsorbate molecule more or less favorable and greatly affects high-coverage behavior. In indirect interactions, the adsorbate changes the surface around the adsorbed site, which in turn affects the adsorption of other adsorbate molecules nearby.
Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion [clarification needed], and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different pha
BET model of multilayer adsorption, that is, a random distribution of sites covered by one, two, three, etc., adsorbate molecules. The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses:
Adsorption is present in many natural, physical, biological and chemical systems and is widely used in industrial applications such as heterogeneous catalysts, [9] [10] activated charcoal, capturing and using waste heat to provide cold water for air conditioning and other process requirements (adsorption chillers), synthetic resins, increasing ...
Water carried into the mantle eventually returns to the surface in eruptions at mid-ocean ridges and hotspots. [8] This circulation of water into the mantle and back is known as the deep water cycle or the geologic water cycle. [9] [10] [11] [5] Estimates of the amount of water in the mantle range from 1 ⁄ 4 to 4 times the water in the ocean ...
Vapor-solid reactions: formation of an inactive surface layer and/or formation of a volatile compound that exits the reactor. [22] This results in a loss of surface area and/or catalyst material. Solid-state transformation : solid-state diffusion of catalyst support atoms to the surface followed by a reaction that forms an inactive phase.
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The Ekman layer near the surface of the ocean extends only about 10 – 20 meters deep, [6] and instrumentation sensitive enough to observe a velocity profile in such a shallow depth has only been available since around 1980. [2] Also, wind waves modify the flow near the surface, and make observations close to the surface rather difficult. [7]