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Two crystalline forms are known, both being very similar to the corresponding potassium sulfate. Orthorhombic β-K 2 CrO 4 is the common form, but it converts to an α-form above 66 °C. [1] These structures are complex, although the chromate ion adopts the typical tetrahedral geometry. [2]
2 CrO 2− 4 + 2 H + ⇌ Cr 2 O 2− 7 + H 2 O. The predominance diagram shows that the position of the equilibrium depends on both pH and the analytical concentration of chromium. [notes 1] The chromate ion is the predominant species in alkaline solutions, but dichromate can become the predominant ion in acidic solutions.
Potassium dichromate, K 2 Cr 2 O 7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health.
CrO 2− 4 + 4 H 2 O + 3 e − → Cr(OH) 3 + 5 OH − (ε 0 = −0.13 V) Sodium chromate (Na 2 CrO 4) Chromium(VI) compounds in solution can be detected by adding an acidic hydrogen peroxide solution. The unstable dark blue chromium(VI) peroxide (CrO 5) is formed, which can be stabilized as an ether adduct CrO 5 ·OR 2. [6] Chromic acid has ...
K 2 CrO 4 + CrO 2 Cl 2 → 2KCrO 3 Cl. The salt consists of the tetrahedral chlorochromate anion. The average Cr=O bond length is 159 pm, and the Cr-Cl distance is ...
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[2] The hashemite crystals are not composed of pure barium chromate but instead contain some small sulfur content as well. The different crystals contain a range of sulfur impurities ranging from the more pure dark crystals, Ba 1.00 (Cr 0.93, S 0.07) 1.00 O 4, to the less pure light crystals, Ba 1.00 (Cr 0.64, S 0.36) 1.00 O 4. [3]