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Elemental fluorine and virtually all fluorine compounds are produced from hydrogen fluoride or its aqueous solution, hydrofluoric acid. Hydrogen fluoride is produced in kilns by the endothermic reaction of fluorite (CaF 2) with sulfuric acid: [169] CaF 2 + H 2 SO 4 → 2 HF(g) + CaSO 4. The gaseous HF can then be absorbed in water or liquefied ...
Organofluorine compounds are pervasive. Many drugs, many polymers, refrigerants, and many inorganic compounds are made from fluoride-containing reagents. Often fluorides are converted to hydrogen fluoride, which is a major reagent and precursor to reagents. Hydrofluoric acid and its anhydrous form, hydrogen fluoride, are particularly important. [4]
Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula H F. It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid .
Solid fluorine carriers", compounds that can release fluorine upon heating, notably cobalt trifluoride, [116] may be used instead, or hydrogen fluoride. After the reaction, the molecular size is not changed significantly, as the elements have very similar van der Waals radii. [114]
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water.Solutions of HF are colorless, acidic and highly corrosive.A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.
This is significantly stronger than the bonds of carbon with other halogens (an average bond energy of e.g. C-Cl bond is around 320 kJ/mol [1]) and is one of the reasons why fluoroorganic compounds have high thermal and chemical stability. The carbon–fluorine bond is relatively short (around 1.4 Å [1]). The Van der Waals radius of the ...
Hydrofluorocarbons (HFCs) are synthetic organic compounds that contain fluorine and hydrogen atoms, and are the most common type of organofluorine compounds. Most are gases at room temperature and pressure.
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...