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The ratio of two extensive properties of the same object or system is an intensive property. For example, the ratio of an object's mass and volume, which are two extensive properties, is density, which is an intensive property. [9] More generally properties can be combined to give new properties, which may be called derived or composite properties.
"Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive ). Regarding work and heat
Density is an intensive property in that increasing the amount of a substance does not increase its density; rather it increases its mass. Other conceptually comparable quantities or ratios include specific density , relative density (specific gravity) , and specific weight .
A system is composed of particles, whose average motions define its properties, and those properties are in turn related to one another through equations of state. Properties can be combined to express internal energy and thermodynamic potentials , which are useful for determining conditions for equilibrium and spontaneous processes .
The three "standard" properties are in fact the three possible second derivatives of the Gibbs free energy with respect to temperature and pressure. Moreover, considering derivatives such as ∂ 3 G ∂ P ∂ T 2 {\displaystyle {\frac {\partial ^{3}G}{\partial P\partial T^{2}}}} and the related Schwartz relations, shows that the properties ...
An intensive property does not depend on the size or extent of the system, nor on the amount of matter in the object, while an extensive property shows an additive relationship. These classifications are in general only valid in cases when smaller subdivisions of the sample do not interact in some physical or chemical process when combined.
Enthalpy is an extensive property; it is proportional to the size of the system (for homogeneous systems). As intensive properties, the specific enthalpy, h = H / m , is referenced to a unit of mass m of the system, and the molar enthalpy, H m = H / n , where n is the number of moles.
Properties of isolated, closed, and open thermodynamic systems in exchanging energy and matter. A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes.