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Free-energy relationship, a relationship in physical organic chemistry; Principle of minimum energy, a thermodynamic formulation based on the second law; Thermodynamic free energy, the energy in a physical system that can be converted to do work, including: Gibbs free energy; Landau free energy (also known as grand potential) Helmholtz free energy
Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [1]
In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature . The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process ...
The energy that a physical body possesses due to its motion, defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. The body continues to maintain this kinetic energy unless its velocity changes. Contrast potential energy. Kirchhoff's circuit laws. Also called Kirchhoff's rules or simply Kirchhoff's laws.
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
A singular term is a paradigmatic referring device in a language. Singular terms are defined as expressions that purport to denote or designate particular individual people, places, or other objects. They contrast with general terms (such as "car" or "chair") which can apply to more than one thing. [1]
The surface energy of a liquid may be measured by stretching a liquid membrane (which increases the surface area and hence the surface energy). In that case, in order to increase the surface area of a mass of liquid by an amount, δA, a quantity of work, γ δA, is needed (where γ is the surface energy density of the liquid).
The component of total energy transfer that accompanies the transfer of vapor into the surrounding subsystem is customarily called 'latent heat of evaporation', but this use of the word heat is a quirk of customary historical language, not in strict compliance with the thermodynamic definition of transfer of energy as heat.