Search results
Results from the WOW.Com Content Network
This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be calculated from tabulated enthalpies of formation and standard molar entropies of reactants and products. [19] [15] The chemical equilibrium condition at constant T and p without electrical work is dG = 0.
Research concerning the relationship between the thermodynamic quantity entropy and both the origin and evolution of life began around the turn of the 20th century. In 1910 American historian Henry Adams printed and distributed to university libraries and history professors the small volume A Letter to American Teachers of History proposing a theory of history based on the second law of ...
In mechanics, the second law in conjunction with the fundamental thermodynamic relation places limits on a system's ability to do useful work. [40] The entropy change of a system at temperature T {\textstyle T} absorbing an infinitesimal amount of heat δ q {\textstyle \delta q} in a reversible way, is given by δ q / T {\textstyle \delta q/T} .
Traditionally, thermodynamics has recognized three fundamental laws, simply named by an ordinal identification, the first law, the second law, and the third law. [1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established.
Most identities in chemical thermodynamics arise from application of the first and second laws of thermodynamics, particularly the law of conservation of energy, to these state functions. The three laws of thermodynamics (global, unspecific forms): 1. The energy of the universe is constant. 2.
Thus, a negative value of the change in free energy is a necessary condition for a process to be spontaneous; this is the most useful form of the second law of thermodynamics in chemistry. In chemical equilibrium at constant T and p without electrical work, d G = 0.
The 2015 NASA strategy on the origin of life aimed to solve the puzzle by identifying interactions, intermediary structures and functions, energy sources, and environmental factors that contributed to the diversity, selection, and replication of evolvable macromolecular systems, [2] and mapping the chemical landscape of potential primordial ...
The third stoichiometric law is the law of reciprocal proportions, which provides the basis for establishing equivalent weights for each chemical element. Elemental equivalent weights can then be used to derive atomic weights for each element. More modern laws of chemistry define the relationship between energy and transformations.