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The bonding occurs through sp 3 hybridized orbitals to give a C-C bond length of 154 pm. This network of unstrained covalent bonds makes diamond extremely strong. Diamond is thermodynamically less stable than graphite at pressures below 1.7 GPa. [5] [6] [7]
Diamond is a solid form of pure carbon with its atoms arranged in a crystal. Solid carbon comes in different forms known as allotropes depending on the type of chemical bond. The two most common allotropes of pure carbon are diamond and graphite.
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) ' other ' and τρόπος (tropos) ' manner, form ') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in structure. If heated over 700 °C (1,292 °F) in air, diamond, being a form of carbon, oxidizes and its surface blackens, but the surface can be restored by re-polishing. [ 47 ]
In diamond, all the carbon-to-carbon bonds, both within a layer of rings and between them, are in the staggered conformation, thus causing all four cubic-diagonal directions to be equivalent; whereas in lonsdaleite the bonds between layers are in the eclipsed conformation, which defines the axis of hexagonal symmetry.
The three relatively well-known allotropes of carbon are amorphous carbon, graphite, and diamond. Once considered exotic, fullerenes are nowadays commonly synthesized and used in research; they include buckyballs , [ 31 ] [ 32 ] carbon nanotubes , [ 33 ] carbon nanobuds [ 34 ] and nanofibers .
According to the researchers, Q-carbon exhibits a random amorphous structure that is a mix of 3-way (sp 2) and 4-way (sp 3) bonding, rather than the uniform sp 3 bonding found in diamonds. [7] Carbon is melted using nanosecond laser pulses, then quenched rapidly to form Q-carbon, or a mixture of Q-carbon and diamond.
Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.