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Likewise, whereas both benzene and naphthalene can be alkylated using Friedel–Crafts reaction conditions, naphthalene can also be easily alkylated by reaction with alkenes or alcohols, using sulfuric or phosphoric acid catalysts. [25] In terms of regiochemistry, electrophiles attack at the alpha position. The selectivity for alpha over beta ...
1-Naphthol, or α-naphthol, is an organic compound with the formula C 10 H 7 OH.It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring.
Ipso-substitution describes two substituents sharing the same ring position in an intermediate compound in an electrophilic aromatic substitution. Trimethylsilyl, tert-butyl, and isopropyl groups can form stable carbocations, hence are ipso directing groups. Meso-substitution refers to the substituents occupying a benzylic position.
The α-carbon (alpha-carbon) refers to the first carbon atom that attaches to a functional group, such as a carbonyl. The second carbon atom is called the β-carbon ( beta -carbon), the third is the γ-carbon ( gamma -carbon), and the naming system continues in alphabetical order.
It is prepared by reduction of 1,5-dinitronaphthalene, which in turn is obtained with the 1,8-isomers by nitration of 1-nitronaphthalene. It can also be prepared by treatment of 1,5-dihydroxynaphthalene with ammonium sulfite. It is a precursor to naphthalene-1,5-diisocyanate, a precursor to specialty polyurethanes. [3]
This colorless solid is soluble in organic solvents. It features a carboxylmethyl group (CH 2 CO 2 H) linked to the "1-position" of naphthalene. Use and regulation
English: Numbering of the carbon atoms in naphthalene molecules according to latest (2013) IUPAC rules P-25.3.2.3 and P-25.3.3.1, which is the same as 1979 rule A-22 Date 13 November 2012, 19:47 (UTC)
Dinitration of naphthalene gives 1,8-dinitronaphthalene, which undergoes hydrogenation to the diamine. The diamine can also be produced by reaction of the 1,8-diol with ammonia at high temperatures. The peri-naphthalene 1-amino-naphthalene-8-sulfonic acid is a precursor to other peri-naphthalenes. It is prepared by nitration of naphthalene-1 ...