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Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar.
Polymer morphology is a microscale property that is largely dictated by the amorphous or crystalline portions of the polymer chains and their influence on each other. Microscopy techniques are especially useful in determining these microscale properties, as the domains created by the polymer morphology are large enough to be viewed using modern ...
For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [30] Crystallinity also affects dyeing of polymers: crystalline polymers are more difficult to stain than amorphous ones because the dye molecules penetrate through amorphous regions with greater ease.
The amorphous polyalphaolefins are synthesized by a catalyst system based on a Z-N supported catalyst and an alkyl aluminum co-catalyst. The polymerization process produces a mostly amorphous polymer with low crystallinity. Crystallinity depends on the catalyst system and on the use of co-monomers.
Polyamorphism is also an important area in pharmaceutical science. The amorphous form of a drug typically has much better aqueous solubility (compared to the analogous crystalline form) but the actual local structure in an amorphous pharmaceutical can be different, depending on the method used to form the amorphous phase.
The crystalline portion has a higher elastic modulus and provides reinforcement for the less stiff, amorphous phase. Polymeric materials can range from 0% to 100% [ 52 ] crystallinity aka volume fraction depending on molecular structure and thermal history.
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is characteristic of a crystal. The terms " glass " and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo ...
Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."