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A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures from corrosion. They are made from a metal alloy with a more "active" voltage (more negative reduction potential / more positive oxidation potential ) than the metal of the structure.
Aluminum sacrificial anodes (light colored rectangular bars) mounted on a steel jacket structure. Zinc sacrificial anode (rounded object) screwed to the underside of the hull of a small boat. Cathodic protection (CP; / k æ ˈ θ ɒ d ɪ k / ⓘ) is a technique used to control the corrosion of a metal surface by making it the cathode of an ...
In this case, sacrificial anodes work as part of a galvanic couple, promoting corrosion of the anode, while protecting the cathode metal. In other cases, such as mixed metals in piping (for example, copper, cast iron and other cast metals), galvanic corrosion will contribute to accelerated corrosion of parts of the system.
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The capacity of a sacrificial metal may be calculated from first principle as follows: 1 kg Al = 1000/27 moles Al; 1 kg Al = 3 x 1000/27 moles of electrons; 1 kg Al = 3 x 1000/27 x 96494 coulombs of charge (by Faraday principles) = 10.72 x 10 6 Amp.seconds of charge per Kg Al (1 Coulomb = 1 Amp.Second) = 10.72 x 10 6 /3600 = 2978 Amp.Hours per Kg
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The difference can be measured as a difference in voltage potential: the less noble metal is the one with a lower (that is, more negative) electrode potential than the nobler one, and will function as the anode (electron or anion attractor) within the electrolyte device functioning as described above (a galvanic cell).
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