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Ionic hydrides are used as bases and, occasionally, as reducing reagents in organic synthesis. [12] C 6 H 5 C(O)CH 3 + KH → C 6 H 5 C(O)CH 2 K + H 2. Typical solvents for such reactions are ethers. Water and other protic solvents cannot serve as a medium for ionic hydrides because the hydride ion is a stronger base than hydroxide and most ...
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
In lithium aluminium hydride, the [AlH 4] − anion carries hydridic centers firmly attached to the Al(III). Although hydrides can be formed with almost all main-group elements, the number and combination of possible compounds varies widely; for example, more than 100 binary borane hydrides are known, but only one binary aluminium hydride. [16]
Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not soluble but reactive with all protic organic solvents. It is soluble and nonreactive with certain molten salts such as lithium fluoride, lithium borohydride, and sodium hydride. With a molar mass of 7.95 g/mol, it is the lightest ionic compound.
Water is the chemical substance with chemical formula H 2 O; one molecule of water has two hydrogen atoms covalently bonded to a single oxygen atom. [26] Water is a tasteless, odorless liquid at ambient temperature and pressure. Liquid water has weak absorption bands at wavelengths of around 750 nm which cause it to appear to have a blue color. [4]
Sodium hydride is the chemical compound with the empirical formula Na H. This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis . NaH is a saline (salt-like) hydride , composed of Na + and H − ions, in contrast to molecular hydrides such as borane , silane , germane , ammonia , and methane .
Calcium hydride is the chemical compound with the formula CaH 2, an alkaline earth hydride. This grey powder (white if pure, which is rare) reacts vigorously with water, liberating hydrogen gas. CaH 2 is thus used as a drying agent, i.e. a desiccant. [2] CaH 2 is a saline hydride, meaning that its structure is salt-like. The alkali metals and ...
The term hydride is probably most often used to describe compounds of hydrogen with other elements in which the hydrogen is in the formal −1 oxidation state. In most such compounds the bonding between the hydrogen and its nearest neighbor is covalent. An example of a hydride is the borohydride anion (BH − 4).