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3,4-Epoxycyclohexylmethyl-3',4'-epoxycyclohexane carboxylate (ECC) is a cycloaliphatic epoxy resin which is used in many industrial applications. It reacts by cationic polymerization using thermolatent photoinitiators to form crosslinked insoluble thermosets.
Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called epoxy. [1] The IUPAC name for an epoxide group is an oxirane.
Vinyl ester resin, or often just vinyl ester, is a resin produced by the esterification of an epoxy resin with acrylic or methacrylic acids. [1] The "vinyl" groups refer to these ester substituents, which are prone to polymerize and thus an inhibitor is usually added.
As an epoxy modifier it is classed as an epoxy reactive diluent. [8] It is one of a family of glycidyl ethers available used for viscosity reduction of epoxy resins. [9] These are then further formulated into coatings, sealants, adhesives, and elastomers. [10] [11] Resins with this diluent tend to show improved workability. [12]
The epoxy value is defined as the number of moles of epoxy group per 100g resin. So as an example using an epoxy resin with molar mass of 382 and that has 2 moles of epoxy groups per mole of resin, the EEW = 382/2 = 191, and the epoxy value is calculated as follows: 100/191 = 0.53 (i.e. the epoxy value of the resin is 0.53). [6]
It is a common monomer used in the production of epoxy resins. While typical home epoxies contain diglycidyl ether of bisphenol A (DGEBA), glycidyl methacrylate is instead used to provide epoxy functionalization to polyolefins and other acrylate resins. Glycidyl methacrylate is produced by several companies worldwide, including Dow Chemical. [2]
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