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The TAG flash point tester adheres to ASTM D56 and has no stirrer, while the Abel flash point testers adheres to IP 170 and ISO 13736 and has a stirring motor so the sample is stirred during testing. The flash point is an empirical measurement rather than a fundamental physical parameter.
The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature (or shortly ignition temperature) and formerly also known as kindling point, of a substance is the lowest temperature at which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. [1]
This allows the development of an equilibrium between the liquid and the air volume. The ignition source is directed into the cup at regular intervals with simultaneous interruption of stirring. The test concludes upon observation of a flash that spreads throughout the inside of the cup. The corresponding temperature is the liquid's flash point.
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Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids. [ 2 ] [ 3 ] Studies show that the actual measure of a liquid's flammability, its flash point, is dependent on the local air pressure, meaning that at higher altitudes where the air pressure is lower, the flash point is also lower.
The technical definitions vary between countries so the United Nations created the Globally Harmonized System of Classification and Labeling of Chemicals, which defines the flash point temperature of flammable liquids as between 0 and 140 °F (60 °C) and combustible liquids between 140 °F (60 °C) and 200 °F (93 °C).
A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions apply:
The fire point, or combustion point, of a fuel is the lowest temperature at which the liquid fuel will continue to burn for at least five seconds after ignition by an open flame of standard dimension. [1] At the flash point, a lower temperature, a substance will ignite briefly, but vapour might not be produced at a rate to sustain the fire ...