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Most analytical instruments produce a signal even when a blank (matrix without analyte) is analyzed.This signal is referred to as the noise level. The instrument detection limit (IDL) is the analyte concentration that is required to produce a signal greater than three times the standard deviation of the noise level.
In the empirical sciences, the so-called three-sigma rule of thumb (or 3 σ rule) expresses a conventional heuristic that nearly all values are taken to lie within three standard deviations of the mean, and thus it is empirically useful to treat 99.7% probability as near certainty.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The detection limit is the level that will lead to false non-detects with a certain probability (say 5%) if the decision is taken at the critical level. Assuming two identical Gaussian distributions (the second one for Ha: analyte present at this level) leads to a detection limit of about 3.30 sigma.
A minimum detectable signal is a signal at the input of a system whose power allows it to be detected over the background electronic noise of the detector system. It can alternately be defined as a signal that produces a signal-to-noise ratio of a given value m at the output.
Nelson rules are a method in process control of determining whether some measured variable is out of control (unpredictable versus consistent). Rules for detecting "out-of-control" or non-random conditions were first postulated by Walter A. Shewhart [1] in the 1920s.
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Simpson and Fitter [3] promoted ′ as the best index, particularly for two-interval tasks, but Das and Geisler [1] have shown that ′ is the optimal discriminability in all cases, and ′ is often a better closed-form approximation than ′, even for two-interval tasks.