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In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
This equal area rule can also be derived by making use of the Helmholtz free energy. [24] In any event the Maxwell construction derives from the Gibbs condition of material equilibrium. However, even though g f = g g {\displaystyle g_{f}=g_{g}} is more fundamental it is more abstract than the equal area rule, which is understood geometrically.
For any complex number written in polar form (such as r e iθ), the phase factor is the complex exponential (e iθ), where the variable θ is the phase of a wave or other periodic function. The phase factor is a unit complex number, i.e. a complex number of absolute value 1. It is commonly used in quantum mechanics and optics.
Euler's formula, named after Leonhard Euler, is a mathematical formula in complex analysis that establishes the fundamental relationship between the trigonometric functions and the complex exponential function.
However, these systems are limiting cases and an exception to the rule. Real phase transitions exhibit power-law behavior. Several other critical exponents, β, γ, δ, ν, and η, are defined, examining the power law behavior of a measurable physical quantity near the phase transition. Exponents are related by scaling relations, such as
Conversely, a phase reversal or phase inversion implies a 180-degree phase shift. [ 2 ] When the phase difference φ ( t ) {\displaystyle \varphi (t)} is a quarter of turn (a right angle, +90° = π/2 or −90° = 270° = −π/2 = 3π/2 ), sinusoidal signals are sometimes said to be in quadrature , e.g., in-phase and quadrature components of a ...
The critical exponents can be derived from the specific free energy f(J,T) as a function of the source and temperature. The correlation length can be derived from the functional F [ J ; T ] . In many cases, the critical exponents defined in the ordered and disordered phases are identical.
There are many correct collections of "Schreinemaker's rules" and the choice to use a given set of rules depends on the nature of the phase diagrams being created. Due to the phrasing of the Morey–Schreinemaker coincidence theorem, only one rule is essential to the Schreinemaker's rules. This is the so-called metastable extensions rule: [1]