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A hydrogen atom with proton and electron spins aligned (top) undergoes a flip of the electron spin, resulting in emission of a photon with a 21 cm wavelength (bottom) The hydrogen line, 21 centimeter line, or H I line [a] is a spectral line that is created by a change in the energy state of solitary, electrically neutral hydrogen atoms.
The amount of energy needed to reverse the spin of the electron is equivalent to a photon at the frequency of 1.420 405 751 768 GHz, [1] which corresponds to the 21 cm line in the hydrogen spectrum. Hydrogen masers are very complex devices and sell for as much as US$235,000 . [ 2 ]
Additionally, the deuterium signal may be used to accurately define 0 ppm as the resonant frequency of the lock solvent and the difference between the lock solvent and 0 ppm (TMS) are well known. Proton NMR spectra of most organic compounds are characterized by chemical shifts in the range +14 to -4 ppm and by spin–spin coupling between protons.
Lyman-alpha, typically denoted by Ly-α, is a spectral line of hydrogen (or, more generally, of any one-electron atom) in the Lyman series.It is emitted when the atomic electron transitions from an n = 2 orbital to the ground state (n = 1), where n is the principal quantum number.
The resonant frequency, energy of the radiation absorbed, and the intensity of the signal are proportional to the strength of the magnetic field. For example, in a 21- tesla magnetic field, hydrogen nuclei ( protons ) resonate at 900 MHz.
Taking for example the H 2 O molecules in liquid phase without the contamination of oxygen-17, the value of K is 1.02×10 10 s −2 and the correlation time is on the order of picoseconds = s, while hydrogen nuclei 1 H at 1.5 tesla precess at a Larmor frequency of approximately 64 MHz (Simplified. BPP theory uses angular frequency indeed).
A simplified version of the Rabi method consists of a beam of atoms, all having the same speed and the same direction, sent through one interaction zone of length .The atoms are two-level atoms with a transition energy of (this is defined by applying a field ‖ in an excitation direction ^, and thus = | ‖ |, the Larmor frequency), and with an interaction time of = / in the interaction zone.
Chemical shift δ is usually expressed in parts per million (ppm) by frequency, because it is calculated from [5] =, where ν sample is the absolute resonance frequency of the sample, and ν ref is the absolute resonance frequency of a standard reference compound, measured in the same applied magnetic field B 0.